Well, not according to the manual.
Please see the generic Fuel page in your owner's manual: (155 in this Skoda one as I don't have the GTI yet)
https://mediaportal.skoda-auto.com/resource/documentation/manuals/en/Fabia/05-2011/Manual/A05_Fabia_OwnersManual.pdfThe bit that interests us GTI users:
Prescribed fuel - unleaded petrol min. 95 RON
Use unleaded petrol with the octane rating 95 RON.
If unleaded petrol with the octane rating 95 RON is not available, you can use petrol with the octane rating 91 RON in an emergency. You must continue driving at medium engine speeds and minimum engine load. High engine revs or a greater engine load can cause major damage to the engine! Refuel as soon as possible with petrol of the prescribed octane number.
Even in case of necessity, you must not use petrol of a lower octane rating than 91 RON, otherwise the engine can be severely damaged!
You can find further information on refuelling page 156, “Refuelling”.
Unleaded petrol with higher octane number
You can make unlimited use of unleaded petrol which has a higher octane number than the one prescribed.
In vehicles with prescribed unleaded petrol 95/91 RON, the use of petrol with a higher octane number than 95 RON does not result in a noticeable power increase or a lower fuel consumption.
On vehicles with prescribed unleaded petrol min. 95 RON, the use of petrol with a higher octane number than 95 RON does not result in a power increase or a lower fuel consumption.Maybe someone who already has the GTI manual can confirm?