what where you compression results? ideally you want in & around 200psi per cylinder
if you are having the head done then do the guides, no need to skim unless overheated as you say, though skim can help lift compression a wee hair also!
all depends how much you wanna do. if you are taking head off you can even change piston rings & big ends with the block & gearbox in place, just remove sump for access