
Black pipe with bolt in the end goes to the charcoal canister
Long blue pipe goes to the airbox, if you haven't got this make sure it is sealed off at the throttle body.
Blue pipe by first spark plug wire goes to the Fuel damper / regulator thingy
Blue pipe above the VW badge on the manifold goes to the ecu. Make sure this is connected at the ecu and not kinked or pinched in between.

Small pipe here is for the ISV make sure it is connected at both ends. One end under the black plastic cover.
Did I read that you haven't put a gasket on the new throttle body, you really need one if you haven't.
I haven't got the vac pipe going under the battery and washer bottle so I don't know what that is for. Mine is a single pipe from the manifold to the brake servo / booster. No piece T'eed off. I will check again later though.
If all above is OK have you tried resetting the ecu. Battery disconnect for 5 to 15 minutes. Also I seem to recall reading about resetting the throttle position switch, after the ecu reset turn the ignition on but don't start the car, you should here some clicking as it sets itself. Don't know if that is rubbish but its free and worth a try if you have fitted a new throttle body.
Good luck
Paul