There’s no harm in trying. However, from what I’ve read on various forums, I do get the impression that since Dieselgate, VW take a firmer line on warranty claims these days, so it may be more difficult to get things such as alloys replaced.
You’ve said the the alloys on your car are in perfect condition. As @Adam T7 has suggested, they may have had harsh cleaning products used on them in the past, especially if the car was regularly washed by one of the many hand car wash places. Those places tend to use harsh cleaning products as it’s a way of removing dirt quickly, meaning they can maximise the number of cars they clean and so generate more income. A tell tale sign of harsh cleaning products having been used on diamond cut alloys might be a cloudy appearance on the diamond cut surface. Alternatively, if the previous owner had the tyres transferred from the Milton Keynes / Parker alloys to their alternative set of alloys and then had the tyres refitted when the OEM alloys were put back on the car, there’s a chance the tyre fitters may have damaged the wheels (quite common) and corrosion has set in.
I personally dislike diamond cut alloys. If they’re on a car all year round IMHO the diamond cut finish isn’t really durable enough to stand up to winter road conditions. They’re also easily damaged by over zealous tyre fitters or poorly maintained tyre changing equipment.
Good luck with trying to get them replaced by VW. If VW decline to replace them, then the cost of a top quality refurbishment is probably around £100 - £120 plus VAT per wheel.
Please keep this discussion thread updated with developments and the outcome.