My Mk5 says 95 Ron on the fuel flap (the same sticker as the Mk6).
That's what it gets in the UK.
When I'm on the Isle of Man I use Shell expensive stuff.
The engine management system is very clever, stuffed with sensors. It just adapts the fuelling and ignition for whatever you put in. The expensive petrol seems to keep the power at peak under all conditions, the 95 Ron can sometimes give a reduced power now and again (if one of the knock sensors reports knocking the ECU acts to look after the engine, straight away).
The biggest difference was after running a full tank of Morrisons I filled with a tank of Asda. The car was really slow for about 15 miles until the ECU had sorted out a decent fuelling/ignition plan.
Next tankful will be Shell expensive on the island. You need every hp you can get to enjoy roads with no speed limit.