I think they continually drip over night until the accumulator and system pressure drops, which I imagine could take some time and a fair amount of fuel. Once the fuel starts pooling on the piston crown I think it must take some time to evaporate, hence squirting that extra fuel in with the extra injector causing even more problems.
The Audi used to start first fire when I got it. Over a period of around 4 years it progressively took longer crank times to start and I started to notice the smell of fuel (flooding). I unplugged that extra injector (after reading an article about said problem in VW-Audi magazine) and sure enough it started straight away. I had that car for 11 years and put 120,000 miles on it. I sold it with 220,000 miles on it, the head had never been off and they were still the original injectors so I guess it's quite possible they were in dire need of replacement.