As a very loose rule of thumb a standard engine "should" hack up to 6 psi of forced induction. For how long though is the real question. It might hack 14psi...... for a week

I've no real experience with FI on VWs so I stand to be corrected but I have a lot of FI experience with Subarus. I tuned 2 of mine to over 375bhp which were both UK spec 208bhp standard.
The garage I worked for also did the first ever supercharger conversion to a n/a Subaru Impreza 2.0 Sport in the UK.
Mad conversion but it's what the owner wanted. That was 135bhp standard and we basically just bolted on a chargecooled supercharger using the standard ECU, injectors and standard block. It ran up to 9psi and did 189bhp on the dyno. The AFR were monitored closely of course, to make sure it didn't lean out and a knock detector was fitted to monitor det. The owner wanted to see exactly how far he could go on the standard lump and was quite prepared to blow it up. At 9psi he was maxing out the OEM injectors so it was left at that but it was a significant improvement over standard.
This was on a 4 year old car though with low mileage etc etc. so although this info is in no way relevant to your car it does give you some idea I suppose.
Also different engines will hack different things. It really is impossible to give you anything other than a ballpark figure.
Take 6psi as a benchmark. It MAY hack more but it MAY also grenade itself on less.
It's a bit like asking "if I'm 24 and start smoking, what's the most no. of fags I can smoke a day to make sure I live past 60."

Who knows?
Hope that helps.