There is a very good possibility that a 90+k mile VR6 will soon need the timing chains replaced - due to a tensioner design flaw. ÂÂÂ
Mine has done 96k miles and i'm starting to get some ominous rattles.  The job is quite involved and costs around £600 and as the gearbox has to come off it would be silly not to replace an original clutch at the same time.
Other than the chains there are no major concerns with a high mileage VR6 as long as it has been well maintained and serviced.
The only other thing i can think of is that the rear axle bushes will probably need replacing on any 90K mile Mk3 if not already done.  Most people seem to have paid between £150 and £250 for this.
One more thing, genuine HT leads cost a fortune - £100+ and most owners concur that cheaper non genuine replacements don't last very long at all.  Although people rate magnecor leads at about £75.
Hope this helps
