The main reason is that earlier cars did not have hardened valve seats which meant that they needed to run aon a lrp subsititure to keep running as they should. The reason 16v are designed for higher octane is that there were engineered with hardened competition valve seats, which meant they could run on the 98 RON stuff, it also allowed them to be run harder and with more revs, whereas the earlier models of car would have begun to get tappety a lot earlier.
The higher octane a petrol is, the lower the chance of pre-ignition, leading to a f**ked head if not careful. My valver definately feels more pokey because of it.