DAN,
I have carried out this as I was having trouble reading settings through VAG-COM.
Its a simple process but you need VAG-COM or alternate, as you have to re program the ECU to the engine.
As for as changing the the lock barrel or immobiliser, you simply recode it to the new ECU. As when you change it without VAG-COM, the car will not start.
Just make sure you get the same part number matched to your engine code.
If you want let me know your Golf year + engine code and I'll see if you have the correct part number for the ECU.