Congrats on the Edition 35 as a 35 owner myself, I know how special they are. A slight lumpy idle when cold isn't uncommon on these, especially as they're direct-injection engines and can be a bit rougher until they're up to temperature.
At 79k miles, a few things I'd be looking at are:
* Spark plugs and coil packs (worth checking when they were last replaced)
* Carbon build-up on the intake valves, which can cause a slightly uneven idle
* PCV valve condition
* Any vacuum leaks
* Fuel injector condition
If it's only for the first minute or so from a cold start and then settles down completely, I wouldn't panic. If you've got access to VCDS/OBDeleven, it would be worth checking for any stored fault codes and looking at misfire counts on each cylinder.
As for fuel, run 99 RON (Tesco Momentum or Shell V-Power) as the Edition 35 was designed around higher-octane fuel. It'll run on 95, but many find it feels a bit smoother and more responsive on 99.
Also, at that mileage I would expect the cam follower to have been replaced.