The score is this...
When the car is running the voltage goes down slowly as the fuel pump sucks the power, also seeing the same voltage drop at the alternator. I've replaced a dodgy looking earth cable to the battery, also replaced the alternator with a known working one. There doesn't appear to be any fuse in the charging circuit, so should I assume the battery is duff? I can find out this on monday if I take it to work and put our fancy tester on it.