Single groove keepers, as it sounds, only have a single groove as opposed to the 3 grooves of the stock set-up. The advantage is that with the single groove the keepers grip the entire circumference of the stem which is much stronger and places less stress on the valve. I really recommend them when exceeding 8000 rpm. You cannot make a 3 groove valve into a single groove one.
Oversize valves are an advantage only when the valve job, and porting is designed to take advantage of them. It is sometimes difficult to get an oversized valve in these heads due to the core shift.
The single groove valves are actually the same price as 3 groove ones, you juts have to buy the keepers to fit. I'm not sure I'd rely on luck to keep an engine together at 9500rpm.