If any of the coolant has frozen, I wouldn't even think of starting the engine until I visually inspected the water pump impeller and bearings, feel test of core plugs on the block, followed by a pressure test on the matrix, radiator and hoses.
A "sniff test" is to check there isn't exhaust fumes/oil in the coolant. If your head/block/HG has cracked/been damaged (however unlikely), then the compression stroke of the piston could well be pressurising the coolant.