If the car has been sat for a number of years, then what are you going to expect? I would get both carbs running properly, then run it hard and get the loose carbon out of the system. Carbon bakes onto the components such as exhaust ports in the cylinder head, the valves and the pistons. But the carbon will soften up and become flakey and burn off with use. This will be the cause of your smoke.
If you think the rings are stuck in their grooves then try, as said before, pouring a little diesel into the bores or some brake fluid and leave to soak over night, then again, run the engine hard and get some heat into it.