no need for the grinder ( yet anyway ) the bolt may have been crosstheaded explaning why it snaped but more likely a hole load of electroltic corosion binding whats left of the bolt to the manifold, sadly golf are getting to the age where these classic car problems start to appear

a good blowtorch is a good freind to have in the workshop so is plenty of plus gas.
heat it them move it about then oil it and then go back to heat. you should notice it start to free up then hopefully all the corrosion will fall out and it'll pop off then you'll wonder what the hell was holding it.