My petrol flap gives one set of figures, as presumably VR6's only had 205/50/15 tyres as standard. Which is what mine has.
Pressures are:
Unloaded - Front 38 Rear 35
Loaded - Front 41 Rear 44
Don't underinflate the tyres as handling, braking and fuel economy will all suffer. If you are running standard wheels/tyres go with what VW put on the car.
Also, the edges of the tyre will wear much quicker with underinflated tyres, as i found out when running 215/40/16s at 30psi.
Overseer, i would use the pressure's you arrived at in the last post, then as soon as one pair of tyres wears out decide if you want 195 or 205 and keep them all the same. Although i'm sure that's your plan anyway. If it helps, my p reg 16v had 205 all round so i would expect that's what yours should have. Only trouble is, 195s are much cheaper than 205s!