Update:
The idle is now much smoother with the vacuum hoses replaced and idle screw adjusted. The smoke might have been WD40 as explained above, or could have been overheating due to blocked radiator - temp gauge was reading ok, but the engine seemed to be running hot, turns out the coolant was rusty orange Manila tap water... A good flush through and refilling with the proper stuff seems to have fixed that.
I haven't got to the fuel filter yet, I am hoping to be able to drive the car to the VW parts shop as its a couple of hours away by bus and jeepney, hopefully only 30 minutes by car.
Eventually I am going to get the aircon compressor looked at too, much too hot here without it!
Can I ask what could be a silly question? The warning light for the catalytic converter keeps flashing, from when I start the car, slowing down when I drive faster. It has done this since I bought the car. What is this likely to mean? Most of the cars I've owned have been pre-cat models so I know very little about them.