My old mk5, and now the R both love V power. I believe that v power is now a 99 RON fuel where previously it was 98. Many of the others top of the range fuel is actual only about 97, bar the Tesco one. Not sure about how many nice additives Tesco will be using, so I stick to Shell for now.
Both my engines are the old type, not really sure your MK6's would not really benefit the extra RON. On mine though, you could definatley tell the difference, they got quite wheezy on 95.
In Germany they've got V Power Racing 100, which has 5% ethanol in it!!!! Boy that stuff is great. Wish they had it here. I remember being a bit shocked at how much quicker I had to change gears! It caught me out a few times and I redlined the poor thing a little too much.