the manifold to downpipe is steel, manifold to head is copper nuts.
manin downpipe comes off quite easy from under the car with plenty of plus gas and 1/2 drive extensions. failing that reg heat and try again.
manifold / head nuts if the head is off and they piss me of i just muder them and then wind the last bit of the stud out. if on the car a good heating till things get a bit red often works