I've ran 20 quids worth of Tesco 99 stuff through also now, same results as V power.
Worse MPG than 95 ron, performance.. I don't really think it's any better or worse overall... think the cold air affects it more!
But, many thanks to Sarah @ Awesome (much appreciated time and effort put in there!) I now know what map is on my car. It's a 95 ron map.
So what do you think guys/experts - stick to 95 ron fuel for increased MPG and identical performance? Especially interested to see if Nick from R-Tech replies

Something else I've noticed on 99 ron fuel is... the engine is a little gruffer/rougher sounding? I'm not convinced it's doing me any favours!

So, if I stick to 95 ron... which is the "best fuel" to use quality wise. Shell is cheap around here... good fuel? Texaco is also cheap, never tried it before. I've ran a lot of Asda fuel and Jet fuel in the Golf, Asda seeming to be smooth and economical. Impressed I was!