Unfortunately i dont have a spare Key, I've had the dash apart for most of this week testing various signals, i've overridden the VAG Immobiliser + The aftermarket one and it still dont start properly.
I have the the Pinout of the ECU and have been testing all signals and everything seems to check out.
Vagcom is now showing no faults either!!

all engine bay earths x4 have been cleaned (didnt need it)
My next step is to replace the Ignition switch with the new part and check out everything throttle related.
I will get to the bottom of this and post here for future reference.
Cheers Steve