Hiya - I've 'heard' that products like Barrs and Radweld should only really be used in emergenices and for as short a time as poss. I gather that the products could possibly block up some of the smaller waterways, especially if there's some build-up in the water-ways.
I don't think that the stuff that does the blocking would help with pitting, as it needs to flow thru a hole in order to build up until it blocks the hole - kinda like platelets in the blood (thinking back many years to school biology)

Is the pitting in such a position that you could use a gasket compound in conjunction with the head gasket?
Cheers,
Dobbs.