You're getting it wrong.
Dot 3, dot 4 and dot 5.1 are poly glycol compounds and dot 5 is silicone.
It's dot 5 that does not absorb water, but silicon is more compressible and hasn't got the lubricating properties of poly glycol so it needs to be used in a system that is designed for dot 5. Dot 5.1 is best for our cars for fast road/track, but it's expensive compared to dot 4, which unless you're real heavy on the brakes will be good enough for fast road.