I believe the theory is that nitrogen molecules are bigger than oxygen molecules and therefore pressure loss through leakage is less; nitrogen does not affect the tyre material as much as oxygen; that pure nitrogen does not contain any moisture, leading to less material corrosion. I could go on, but try googling "nitrogen in tyres" and have a read. It may be worth a try for aircraft tyres where safety is a priority and F1 car tyres where cost is of little consequence and the odd point one of a second really matters, but I'll stick with the 78% mix I get free from petrol station air lines.
Some people say it's just an opportunity for the tyre fitters to make a bit more money by charging you for pure nitrogen top ups from time to time, but i can't believe that could be true!!!!!!!!!
h8v.