Sorted
Disconnected the hoses from the inner rad and found that to be completly empty. Filled that to the until i had a constant flow of water out of the rad and reconnected the hoses. Filled the system up and squeezed any hoses i could to remove any air from system. When i was happy that it was no longer airlocked put the lid on the expansion tank on tightly again and just monitored the car for a few minutes.
After a min or two water started to pour out of the vent on the side of the expansion bottle. Thought this was normal as i had filled the bottle above the max line. Thought it would settle eventually but it didnt. Unscrewed the lid again and found that there was no release of pressure when the cap lid was opened, system obviously wasnt pressurising. The seal on lid has shifted slightly, realigned it, refitted cap and hey presto water stopped coming out of the vent of the expansion bottle.
Only had the car back a few days, the only reason i didnt suspect the water coming out of the expansion cap was because i was intentially over filling it to be sure id had enough coolant to get to / from work. By the time id get home and look for leaks the water would have stopped coming out of the expansion bottle and the system airlocked.
Such a simple fix in the end