I've seen this on other motoring sites for some time but I've only recently heard the radio info, I'm just inside the area covered by TfL and they are warning you check if your car if it's before 2011!
AFAIK even the SUL petrol will go to E10, I think there only one or two companies (??ESSO) that still have non-bio SUL, otherwise you'll have no choice.
From what I gather turbo engines produce more power on bio-fuels but at a risk of eating your fuel lines on the older cars!
Having looked into more today and seen a few comments on subject across other forums, it does seem to be a pre-2011 issue and majority of cars past that will have no issues both in running, performance and longevity - however its not uncommon to see many cars in the 07-11 plate range, and they could be quite compromised in getting E5 fuel (despite promises)
"With the exception to those models listed below, which used the first generation FSI engines, E10 is cleared for use in all Volkswagen petrol engine vehicles.
Bora - 1.6 litre (81kW) FSI Saloon and Estate made from October 2001 to September 2005
Golf mark 4 - 1.6 litre (81kW) FSI made from November 2001 to May 2004
Golf mark 4 Estate - 1.6 litre (81kW) FSI made from October 2001 to October 2006
Golf mark 5 - 1.4 litre (66kW) FSI made from November 2003 to November 2004
Golf mark 5 - 1.6 litre (85kw) FSI made from August 2003 to May 2004
Golf mark 5 2.0 litre (110 kW) FSI made from January 2004 to May 2004
Lupo – 1.4 litre (77kW) FSI made from August 200 to November 2003
Polo – 1.4 litre (63kW) FSI made from February 2002 to June 2006
Touran – 1.6 litre (85kW) FSI made from November 2002 to May 2004
Touran – 2.0 litre (110kW) FSI made from October 2003 to May 2004"
So just keep to the right octane and you'll be fine eg 95, 97 or if you're luck enough to get it 98/99.