As mentioned before in tuned cars I think it does make a difference, a friend of mine with a tuned Scooby will not run on supermarket fuel, he was running low and put a tenner in the car wouldn't idle having to keep the revs up to stop it stalling, and then it wouldn't pull away (it was remapped with nitro+ in tho)
In our golfs tho Ive just changed over to the nitro+ from just Morrison petrol and I think I am getting better mpg, before I wouldn't get over 40mpg but today tank and half of the stuff later sitting at 65 on the motorway with 2 bikes on the roof got 44
Id say give it ago, its only a fiver more for a full tank (my local nitro+ is 10p a litre more then Morrison) make your own mind up as im planned for remap soon im gonna be sticking with the nitro+