I'm not a mk6 GTI owner, but I did own a mk6 GTD so can answer the 2nd and 3rd questions you've asked.
Bi-xenons were an optional extra on the GTI (ex ED 35 model). They were standard on the ED 35 anniversary model. I had them on my mk6 GTD and they were great. They were quite a costly option, so not too many GTI's had them.
Rear LED's were introduced as standard sometime during 2010 for model year 2011 cars (the GTD I test drove in Oct 2010 had them).
There will be many discussion threads within the mk6 section of the forum on fuel consumption. Suggest you use the search function and you should get an idea of typically what you could expect to achieve.
Some current / past mk6 GTI owners on the forum will probably advise you further on the tensioner issue. Some cars with the original version (or early revisions) of the tensioner will have had these replaced for the latest version. If considering buying an earlier version of the mk6 GTI, always check if the tensioner has been replaced and asked to see evidence of this - don't just rely on word of mouth. If it's not been done, use this to negotiate an appropriate reduction in the car's selling price.